This will broadcast on ITV 4 simultaneously with the broadcast via TNT in the States starting 2 October 2019
It will air on Sunday October 6 at 8.20am not exactly prime time although it will be a two hour show. A one hour edited show will air at 11.45pm on the Monday, so you can watch MLW at 10.30pm on frees port Channel then flip to ITV4 if you so desire.